Waxes Definition/Type/Properties
What is wax?
 

Wax is a generic term for a range of natural or synthetic products. For convenience the range can be subdivided:

  • Natural waxes
  • Synthetic waxes
  • Mineral hydrocarbon waxes
  • Petroleum waxes

Definition
 

Waxes are usually defined by their characteristic properties (see also International Customs Tariff, Harmonized System HS 3404):

  • solid at 20° C, varying in consistency from soft and plastic to brittle and hard
  • as solids as coarse to finely crystalline, transparent to opaque, but not glass-like
  • have relatively low viscosity slightly above the melting point
  • melt above ca. 40° C without decomposition
  • consistency and solubility are highly temperature dependant
  • buffable under slight pressure
  • burn with yellow flame
  • can form pastes or gels when dispersed in solvents
  • exhibit low thermal and electrical conductivity

Type of Waxes
 

Natural (non fossil) Waxes

The natural wax can be of vegetable or animal origin.
The predominant wax of animal origin is beeswax (E 901). The most important representatives of vegetable origin are: 
  • carnaœba (E 903)
  • candelilla (E 902)

Mineral Hydrocarbon Waxes

  • Montan Wax - derived by solvent extraction of lignite
  • Ozo Kerite

Petroleum Waxes

Petroleum waxes are hydrocarbons derived from petroleum. There are four main types: 
  • slack wax - unextracted wax derived from dewaxing base distillate lub oil streams
  • paraffin - deoiled slack wax consisting predominantly of straight chain alkanes
  • microcrystalline (E 905) - branched and cyclic alkanes from deoiling residual bright stock lube oil stream
  • petrolatum - bright stock deoiled residual lube oil or blends of oils and waxes - petroleum jellies

Synthetic Waxes 

  • polyolefin waxes
  • Fischer-Tropsch wax

 

Funktion and Effect of Waxes
  • flatting in paint systems
  • fuel in candles and firelogs
  • mold release
  • lubrication in plastic procession
  • protection against UV attack in rubber
  • coating and lamination in flexible packaging
  • moisture proofing in fibre and chipboard
  • pigment carrier for colour concentrates and dispersions 
  • imparting gloss and protection in polishes
  • viscosity regulation in hot melt adhesives
 
  For more details, please refer to review articles such as "Waxes", Ullmann's Encyclopedia, Vol. A 28, VCH Verlagsgesellschaft, 1996.

Methods
For any characteristic that has not been adequately described in ASTM or other internationally standardized methods, the EWF proposes a suitable test as developed by its members. So far, two tests are available:  

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Standard Test Method for Analysis of Hydrocarbon Waxes by Chromatography (EWF Method 001/03)

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Standard Method for Analysis of Benzene and Toluene Content in Hydrocarbon Waxes by Headspace Gas Chromatography (EWF Method 002/03)